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Photocatalytic conversion of cellulose into C5 oligosaccharides. (2023)
Journal Article
SKILLEN, N., WELGAMAGE, A., ROBERTSON, P.K.J., IRVINE, J.T.S. and LAWTON, L.A. 2023. Photocatalytic conversion of cellulose into C5 oligosaccharides. Journal of physics: energy [online], 6(1), article number 015002. Available from: https://doi.org/10.1088/2515-7655/ad04f1

Cellulose is made up of linear polymers of glucose monomers that could be a crucial source for valuable chemicals and sustainable liquid fuels. Cellulose is however, very stable and its conversion to a useful fuel or platform chemical products remain... Read More about Photocatalytic conversion of cellulose into C5 oligosaccharides..

Bio-based sustainable polymers and materials: from processing to biodegradation. (2023)
Journal Article
OKOLIE, O., KUMAR, A., EDWARDS, C., LAWTON, L.A., OKE, A., MCDONALD, S., THAKUR, V.K. and NJUGUNA, J. 2023. Bio-based sustainable polymers and materials: from processing to biodegradation. Journal of composites science [online], 7(6), article 213. Available from: https://doi.org/10.3390/jcs7060213

In the life cycle of a material, there will be either chemical or physical change due to varying environmental factors such as biological activity, light, heat, moisture, and chemical conditions. This process leads to polymer property change as perta... Read More about Bio-based sustainable polymers and materials: from processing to biodegradation..

Using cellulose polymorphs for enhanced hydrogen production from photocatalytic reforming. (2019)
Journal Article
CHANG, C., SKILLEN, N., NAGARAJAN, S., RALPHS, K., IRVINE, J.T.S., LAWTON, L. and ROBERTSON, P.K.J. 2019. Using cellulose polymorphs for enhanced hydrogen production from photocatalytic reforming. Sustainable energy and fuels [online], 3(8), pages 1971-1975. Available from: https://doi.org/10.1039/c9se00377k

Efficient energy production and waste valorisation are the most challenging fields in photocatalysis. Reported here is enhanced hydrogen production from cellulose, achieved through the conversion of cellulose I to II via a simple pretreatment step.

A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis. (2017)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2017. A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis. Journal of environmental chemical engineering [online], 5(4), pages 3942-3948. Available from: https://doi.org/10.1016/j.jece.2017.07.068

A novel photocatalytic reactor based on a stirred tank configuration has been described. This reactor employs the use of photocatalytic impellers to aid the mass transport of gaseous organic compounds during photocatalytic reactions. Experiments invo... Read More about A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis..

Controlled periodic illumination in semiconductor photocatalysis. (2015)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2015. Controlled periodic illumination in semiconductor photocatalysis. Journal of photochemistry and photobiology A: chemistry [online], 319-320, pages 96-106. Available from: https://doi.org/10.1016/j.jphotochem.2015.12.002

Controlled periodic illumination is a hypothesis postulated in the early 1990s for enhancing the efficiency of semiconductor photocatalytic reactions. This technique has been proposed to improve photocatalytic efficiency by the nature of photon intro... Read More about Controlled periodic illumination in semiconductor photocatalysis..

Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination. (2014)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2014. Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination. Applied catalysis B: environmental [online], 156-157, pages 398-403. Available from: https://doi.org/10.1016/j.apcatb.2014.03.046

Quantum yields of the photocatalytic degradation of methyl orange under controlled periodic illumination (CPI) have been modelled using existing models. A modified Langmuir-Hinshelwood (L-H) rate equation was used to predict the degradation reaction... Read More about Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination..

The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources. (2014)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2014. The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources. Chemical engineering journal [online], 246, pages 337-342. Available from: https://doi.org/10.1016/j.cej.2014.03.002

The nature of photon interaction and reaction pH can have significant impacts on semiconductor photocatalysis. This paper describes the effect of pH on the photonic efficiency of photocatalytic reactions in the aqueous phase using TiO2 catalysts. The... Read More about The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources..

Effect of controlled periodic-based illumination on the photonic efficiency of photocatalytic degradation of methyl orange. (2012)
Journal Article
TOKODE, O.I., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2012. Effect of controlled periodic-based illumination on the photonic efficiency of photocatalytic degradation of methyl orange. Journal of catalysis [online], 290, pages 138-142. Available from: https://doi.org/10.1016/j.jcat.2012.03.011

The use of controlled periodic illumination with UV LEDs for enhancing photonic efficiency of photocatalytic decomposition processes in water has been investigated using methyl orange as a model compound. The impact of the length of light and dark ti... Read More about Effect of controlled periodic-based illumination on the photonic efficiency of photocatalytic degradation of methyl orange..