Seasonal fluxes and sources apportionment of dissolved inorganic nitrogen wet deposition at different land-use sites in the Three Gorges reservoir area.

Cui, Jian; Zhang, Yuanzhu; Yang, Fumo; Chang, Yajun; Du, Ke; Chan, Andy; Yao, Dongrui

Abstract

To identify seasonal fluxes and sources of dissolved inorganic nitrogen (DIN) wet deposition, concentrations and δ15N signatures of nitrate (NO3−) and ammonium (NH4+) in wet precipitation were measured at four typical land-use types in the Three Gorges reservoir (TGR) area of southwest China for a one-year period. Higher DIN fluxes were recorded in spring and summer and their total fluxes (averaged 7.58 kg N ha−1) were similar to the critical loads in aquatic ecosystems. Significant differences of precipitation δ15N were observed for NH4+-N between town and wetland sites in spring and between urban and rural sites in summer. For NO3−-N, significant differences of precipitation δ15N were observed between town and rural sites in spring and between urban and town sites in autumn, respectively. Quantitative results of NO3−-N sources showed that both biomass burning and coal combustion had higher fluxes at the urban site especially in winter (0.18 ± 0.09 and 0.19 ± 0.08 kg N ha−1), which were about three times higher than those at the town site. A similar finding was observed for soil emission and vehicle exhausts in winter. On the whole, DIN wet deposition averaged at 12.13 kg N ha−1 yr−1 with the urban site as the hotspot (17.50 kg N ha−1 yr−1) and regional NO3−-N fluxes had a seasonal pattern with minimum values in winter. The contribution to NO3−-N wet deposition from biomass burning was 26.1 ± 14.1%, which is the second dominant factor lower than coal combustion (26.5 ± 12.6%) in the TGR area during spring and summer. Hence N emission reduction from biomass burning, coal combustion and vehicle exhausts should be strengthened especially in spring and summer to effectively manage DIN pollution for the sustainable development in TGR area.

Citation

CUI, J., ZHANG, Y., YANG, F., CHANG, Y., DU, K., CHAN, A. and YAO, D. 2020. Seasonal fluxes and sources apportionment of dissolved inorganic nitrogen wet deposition at different land-use sites in the Three Gorges reservoir area. Ecotoxicology and environmental safety [online], 193, article 110344. Available from: https://doi.org/10.1016/j.ecoenv.2020.110344

• Journal Article Type: Article
• Acceptance Date: Feb 14, 2020
• Online Publication Date: Feb 21, 2020
• Publication Date: Apr 15, 2020
• Deposit Date: Jun 30, 2023
• Publicly Available Date: Jul 6, 2023
• Journal: Ecotoxicology and Environmental Safety
• Print ISSN: 0147-6513
• Electronic ISSN: 1090-2414
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 193
• Article Number: 110344
• DOI: https://doi.org/10.1016/j.ecoenv.2020.110344
• Keywords: Inorganic nitrogen; Nitrogen isotope; Wet deposition; Source apportionment; Three Gorges reservoir (TGR)
• Public URL: https://rgu-repository.worktribe.com/output/1998296
• Additional Information: This article has been published with separate supporting information. This supporting information has been incorporated into a single file on this repository and can be found at the end of the file associated with this output.