Batch process esterification of lactic acid catalysed by cation-exchange resins for the production of environmental-friendly solvent.

Okon, Edidiong; Habiba, Shehu; Gobina, Edward

Abstract

In this work, batch wise esterification of lactic acid and ethanol was carried out using different cation-exchange resins including amberlyst 15, amberlyst 16, dowex 50W8x and amberlyst 36 as heterogeneous catalysts. The Zeiss EVO LS10 Scanning electron microscopy/energy dispersive x-ray analyser (SEM/EDXA) was used to examine the surface morphology of the resin catalysts before and after the esterification reaction process. The EDXA of the catalysts showed the presence of sulphur with the highest peak on the spectra. The SEM of the commercial resin catalysts showed a clear surface with no crack before the esterification reaction. Amberlyst 36 showed a greater thermal stability after the esterification reaction process. The order of the surface integrity from the SEM morphology of the resin catalysts after the esterification process was Amberlyst 36 > dowex 50W8x. Gas chromatography equipped with mass spectrometry (GC- MS) detector was used to analyse the reaction products. Ion 45 on the mass spectra confirmed that the esterification product was in accordance with the library mass spectra of the commercial ethyl lactate solvent. The agitation time was found to increase with increase in concentration indicating a non-mass transfer limitation at 60 oC. The reaction product catalysed with amberlyst 36 was found to elute at faster at 1.441 min in contrast to the commercial ethyl lactate solvent at 2.124 min indicating a higher reaction rate of the resin catalysts.

Citation

EDIDIONG, O., HABIBA, S. and GOBINA, E. 2015. Batch process esterification of lactic acid catalysed by cation-exchange resins for the production of environmental-friendly solvent. In Ao, S.I., Gelman, L., Hukins, D.W.L., Hunter, A. and Korsunsky, A.M. (eds.) Proceedings of the 2015 World congress on engineering and computer science 2015 (WCECS 2015), 21-23 October 2015, San Francisco, USA. Lecture notes in engineering and computer science, 2220. Hong Kong: Newswood Limited [online], pages 623-628. Available from: http://www.iaeng.org/publication/WCECS2015/WCECS2015_pp623-628.pdf

• Presentation Conference Type: Conference Paper (published)
• Conference Name: 2015 World congress on engineering and computer science (WCECS 2015)
• Start Date: Oct 21, 2015
• End Date: Oct 23, 2015
• Acceptance Date: Aug 6, 2015
• Online Publication Date: Oct 21, 2015
• Publication Date: Oct 23, 2015
• Deposit Date: Mar 23, 2017
• Publicly Available Date: Mar 23, 2017
• Print ISSN: 2078-0958
• Electronic ISSN: 2078-0966
• Publisher: Newswood Academic Publishing
• Peer Reviewed: Peer Reviewed
• Pages: 623-628
• Series Title: Lecture notes in engineering and computer science
• Series Number: 2220
• Series ISSN: 2078-0966
• ISBN: 9789881404725
• Keywords: Esterification; Lactic acid; Cation exchange resin; Ethyl lactate; Chromatogram; Ethanol
• Public URL: http://hdl.handle.net/10059/2236
• Publisher URL: http://www.iaeng.org/publication/WCECS2015/
• Contract Date: Mar 23, 2017