Renato Gil
Study of a novel bisnaphthalimidopropyl polyamine as electroactive material for perchlorate-selective potentiometric sensors.
Gil, Renato; Amorim, C�lia G.; Crombie, Laura; Kong Thoo Lin, Paul; Ara�jo, Alberto; da Concei��o Montenegro, Maria
Authors
C�lia G. Amorim
Laura Crombie
Paul Kong Thoo Lin
Alberto Ara�jo
Maria da Concei��o Montenegro
Abstract
In this work, the new polyamine bisnaphthalimidopropyl-4,4'-diaminodiphenylmethane is proposed as a new ionophore for perchlorate potentiometric sensors. The optimal formulation for the membrane comprised of 12mmolkg-1 of the ionophore, and 68% (w/w) of 2-nitrophenyl phenyl ether as plasticizer and 31% (w/w) of high molecular weight PVC. The sensors were soaked in water for a week to allow leakage of anionic impurities and for one day in a perchlorate solution (10-4molL-1) to improve reproducibility due to its first usage. The stability constant for the ionophore-perchlorate association in the membrane, log βIL1=3.18±0.04, ensured a performance characterized by the slope of 54.1 (±0.7) mVdec-1 to perchlorate solutions with concentrations between 1.24×10-7 and 1.00×10-3molL-1. The sensors are insensitive to pH between 3.5 to 11.0, they have a practical detection limit of 7.66 (±0.42) ×10-8molL-1 and a response time below 60s for solutions with perchlorate concentrations above 5×10-6molL-1. The accuracy of the results was confirmed by the analysis of the contaminant in a certified reference water sample.
Citation
GIL, R., AMORIM, C.G., CROMBIE, L., KONG THOO LIN, P., ARUJO, A. and da CONCEICAO MONTENEGRO, M. 2015. Study of a novel bisnaphthalimidopropyl polyamine as electroactive material for perchlorate-selective potentiometric sensors. Electroanalysis [online], 27(12), pages 2809-2819. Available from: https://doi.org/10.1002/elan.201500275
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 20, 2015 |
Online Publication Date | Jul 16, 2015 |
Publication Date | Dec 31, 2015 |
Deposit Date | Sep 19, 2016 |
Publicly Available Date | Sep 19, 2016 |
Journal | Electroanalysis |
Print ISSN | 1040-0397 |
Electronic ISSN | 1521-4109 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 27 |
Issue | 12 |
Pages | 2809-2819 |
DOI | https://doi.org/10.1002/elan.201500275 |
Keywords | Bisnaphthalimidopropyl polyamine; Potentiometry; Sensors; Perchlorate; Waters |
Public URL | http://hdl.handle.net/10059/1778 |
Contract Date | Sep 19, 2016 |
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