Core-double shell hybrid nanocomposites as multi-functional advanced materials.

Khobragade, Prashant S.; Hansora, D.P.; Naik, Jitendra B.; Njuguna, James; Mishra, Satyendra

Abstract

In this research work, we report circular type silane-modified CaCO3 (as core) nanoparticles (NP) encapsulated with polystyrene (PS) and polymethyl methacrylate (PMMA) (as double shell layers). These core-double shell [CaCO3-PS/PMMA] hybrid nanostructures were prepared by a stepwise micro-emulsion polymerization and characterized by fourier transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, field emission scanning electron microscopy, elemental mapping, differential scanning calorimetry and thermo gravimetric analysis. These core-double shell hybrid nanostructured composites had perfect nanoscale shape with narrow size distribution (average size 120 nm), smooth surface and non-agglomerated structures. These observations reflected the strong interfacial interaction between silanated CaCO3-NPs and polymer NPs, which imply the successful grafting of polymer chains onto the surface of silane-modified CaCO3-NPs.

Citation

KHOBRAGADE, P.S., HANSORA, D.P., NAIK, J.B., NJUGUNA, J. and MISHRA, S. 2017. Core-double shell hybrid nanocomposites as multi-functional advanced materials. Polymer bulletin [online], 74(11), pages 4681-4700. Available from: https://doi.org/10.1007/s00289-017-1983-5

• Journal Article Type: Article
• Acceptance Date: Mar 14, 2017
• Online Publication Date: Mar 20, 2017
• Publication Date: Nov 30, 2017
• Deposit Date: May 18, 2017
• Publicly Available Date: Mar 21, 2018
• Journal: Polymer Bulletin
• Print ISSN: 0170-0839
• Electronic ISSN: 1436-2449
• Publisher: Springer
• Peer Reviewed: Peer Reviewed
• Volume: 74
• Issue: 11
• Pages: 4681-4700
• DOI: https://doi.org/10.1007/s00289-017-1983-5
• Keywords: Coredouble shell nanostructures; Hybrids; Multifunctional properties; Characterisation
• Public URL: http://hdl.handle.net/10059/2319