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Determination of cure mechanism inside die for a part manufacturing during large-scale pultrusion.

Mukherji, Arindam; Tarapore, Nozer; Njuguna, James

Authors

Arindam Mukherji

Nozer Tarapore



Abstract

The cure kinetics of resin, heat capacity and thermal conductivity of reinforcing materials of uncured mass dictates the ultimate curing of reinforced thermosets manufactured component. In this study, degree of conversion from heat capacity by ‘Lumry and Eyring Model’ and order of reaction by multi-regression technique using ‘Borchardt and Daniels Model’ are calculated in finding cure kinetics (ɣ) of the resin. Experimental results from differential scanning calorimetry (DSC), thermogravimetry (TGA) and rheological measurements were used to determine thermal conductivity, heat capacity and rheological parameters of the resin through several model fitting. The calculated thermal conductivity of uncured composite from ration of (length vs contact area) and thermal resistivity extracted from TGA data was fitted into specific mathematical model which predicts the thermal behaviour of heated prepreg during pultrusion operation. These parameters used in a separate mathematical partial differential equation-based model equation to predict the change in temperature and resin conversion along axial distance and radial thickness. The influence of operating conditions, such as rate of heating (Early and late Heating) and fibre volume fraction while curing inside die were calculated and validated with experimental results. This study evaluates the extent of heat transfer and degree of conversion inside pultrusion die during scale up steady state process. It is observed that paradigm of influencing parameters like pulling speed, die radial thickness and heater engagement (Early and late heating) on heat flow from die wall to core (i.e., thickness of the part being pulled) follows the data captured experimentally.

Citation

MUKHERJI, A., TARAPORE, N. and NJUGUNA, J. 2022. Determination of cure mechanism inside die for a part manufacturing during large-scale pultrusion. Journal of applied polymer science [online], 139(17), article 52035. Available from: https://doi.org/10.1002/app.52035

Journal Article Type Article
Acceptance Date Nov 3, 2021
Online Publication Date Dec 18, 2021
Publication Date May 5, 2022
Deposit Date Dec 10, 2021
Publicly Available Date Dec 19, 2022
Journal Journal of Applied Polymer Science
Print ISSN 0021-8995
Electronic ISSN 1097-4628
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 139
Issue 17
Article Number 52035
DOI https://doi.org/10.1002/app.52035
Keywords Cure kinetics; Resin; Thermal conductivity; Heat transfer; Curing mechanism; Manufacturing; Polyesters; Pultrusion; Rheology; Synthesis and processing techniques
Public URL https://rgu-repository.worktribe.com/output/1545129

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MUKHERJI 2022 Determination of cure (AAM) (1.3 Mb)
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Publisher Licence URL
https://creativecommons.org/licenses/by-nc-nd/4.0/

Copyright Statement
This is the peer reviewed version of the following article: MUKHERJI, A., TARAPORE, N. and NJUGUNA, J. 2022. Determination of cure mechanism inside die for a part manufacturing during large-scale pultrusion. Journal of applied polymer science [online], 139(17), article 52035, which has been published in final form at https://doi.org/10.1002/app.52035. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.




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