Thermo-physical behaviour of thermoplastic composite pipe for oil and gas applications.

Okolie, Obinna; Faisal, Nadimul Haque; Jamieson, Harvey; Mukherji, Arindam; Njuguna, James

Abstract

Thermoplastic composite pipes (TCP) consist of three distinct layers—liner, reinforcement, and coating—offering superior advantages over traditional industrial pipes, including flexibility, lightweight construction, and corrosion resistance. This study systematically characterises the thermal properties of TCP layers and their compositions using a multi-method approach. Thermal analysis was conducted through differential scanning calorimetry (DSC) for isothermal and non-isothermal crystallisation, thermogravimetric analysis (TGA) for thermal stability, and Fourier transform infrared spectroscopy (FTIR) for material identification. FTIR confirmed polyethylene as the primary component of TCP, with compositional variations across the layers. TGA results indicated that thermal degradation begins at approximately 200°C, with complete decomposition at 500°C. DSC analysis revealed a double melting peak, prompting further investigation into its mechanisms. On-isothermal crystallisation kinetics, analysed at cooling rates of 10°C/min and 50°C/min, revealed an anisotropic crystalline growth pattern. Although nucleation occurs uniformly, the subsequent three-dimensional crystalline growth is governed more by the degree of supercooling than by the crystallography of the glass fibres. This underscores the importance of precisely controlling the cooling rate during manufacturing to optimise the anisotropic properties of the reinforced layer. This study also demonstrates the value of FTIR, TGA, and DSC techniques in characterising the thermo-physical behaviour of TCP, offering critical insights into thermal expansion, shrinkage phenomena, and overall material stability. Given the limited body of research on this specific TCP formulation, the findings presented here lay a foundation for both quality enhancement and process optimisation. Moreover, the paper offers a distinctive perspective on the dynamic behaviour, thermal expansion, and long-term performance of TCP in demanding oil and gas environments.

Citation

OKOLIE, O., FAISAL, N.H., JAMIESON, H., MUKHERJI, A. and NJUGUNA, J. 2025. Thermo-physical behaviour of thermoplastic composite pipe for oil and gas applications. Polymers [online], 17(8), article number 1107. Available from: https://doi.org/10.3390/polym17081107

• Journal Article Type: Article
• Acceptance Date: Mar 28, 2025
• Online Publication Date: Apr 19, 2025
• Publication Date: Apr 30, 2025
• Deposit Date: May 8, 2025
• Publicly Available Date: May 8, 2025
• Journal: Polymers
• Electronic ISSN: 2073-4360
• Publisher: MDPI
• Peer Reviewed: Peer Reviewed
• Volume: 17
• Issue: 8
• Article Number: 1107
• DOI: https://doi.org/10.3390/polym17081107
• Keywords: Non-isothermal crystallinity; Thermal stability; Melt behaviour; Functional group; Crystallisation kinetics; Anisotropy
• Public URL: https://rgu-repository.worktribe.com/output/2801777