A continuous flow packed bed photocatalytic reactor for the destruction of 2-methylisoborneol and geosmin utilising pelletised TiO2.

Pestana, Carlos J.; Robertson, Peter K.J.; Edwards, Christine; Wilhelm, Willem; McKenzie, Craig; Lawton, Linda A.

doi:10.1016/j.cej.2013.09.041

Enhancing photocatalytic degradation of the cyanotoxin microcystin-LR with the addition of sulfate-radical generating oxidants. (2018)
Journal Article
ANTONIOU, M.G., BORAEI, I., SOLAKIDOU, M., DELIGIANNAKIS, Y., ABHISHEK, M., LAWTON, L.A. and EDWARDS, C. 2018. Enhancing photocatalytic degradation of the cyanotoxin microcystin-LR with the addition of sulfate-radical generating oxidants. Journal of hazardous materials [online], 360, pages 461-470. Available from: https://doi.org/10.1016/j.jhazmat.2018.07.111

This study investigated the coupling of sulfate radical generating oxidants, (persulfate, PS and peroxymonosulfate, PMS) with TiO2 photocatalysis for the degradation of microcystin-LR (MC-LR). Treatment efficiency was evaluated by estimating the elec... Read More about Enhancing photocatalytic degradation of the cyanotoxin microcystin-LR with the addition of sulfate-radical generating oxidants..

Cell lysis and detoxification of cyanotoxins using a novel combination of microbubble generation and plasma microreactor technology for ozonation. (2018)
Journal Article
PANDHAL, J., SISWANTO, A., KUVSHINOV, D., ZIMMERMAN, W.B., LAWTON, L. and EDWARDS, C. 2018. Cell lysis and detoxification of cyanotoxins using a novel combination of microbubble generation and plasma microreactor technology for ozonation. Frontiers in microbiology [online], 9, article number 678. Available from: https://doi.org/10.3389/fmicb.2018.00678

There has been a steady rise in the global incidences of algal blooms and, worryingly, there is increasing evidence that changes in the global climate are leading to a shift toward cyanobacterial blooms. Many cyanobacterial genera are harmful, produc... Read More about Cell lysis and detoxification of cyanotoxins using a novel combination of microbubble generation and plasma microreactor technology for ozonation..

Development and single-laboratory validation of a UHPLC-MS/MS method for quantitation of microcystins and nodularin in natural water, cyanobacteria, shellfish and algal supplement tablet powders. (2017)
Journal Article
TURNER, A.D., WAACK, J., LEWIS, A., EDWARDS, C. and LAWTON, L. 2018. Development and single-laboratory validation of a UHPLC-MS/MS method for quantitation of microcystins and nodularin in natural water, cyanobacteria, shellfish and algal supplement tablet powders. Journal of chromatography B [online], 1074-1075, pages 111-123. Available from: https://doi.org/10.1016/j.jchromb.2017.12.032

A simple, rapid UHPLC-MS/MS method has been developed and optimised for the quantitation of microcystins and nodularin in wide variety of sample matrices. Microcystin analogues targeted were MC-LR, MC-RR, MC-LA, MC-LY, MC-LF, LC-LW, MC-YR, MC-WR, [As... Read More about Development and single-laboratory validation of a UHPLC-MS/MS method for quantitation of microcystins and nodularin in natural water, cyanobacteria, shellfish and algal supplement tablet powders..

A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis. (2017)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2017. A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis. Journal of environmental chemical engineering [online], 5(4), pages 3942-3948. Available from: https://doi.org/10.1016/j.jece.2017.07.068

A novel photocatalytic reactor based on a stirred tank configuration has been described. This reactor employs the use of photocatalytic impellers to aid the mass transport of gaseous organic compounds during photocatalytic reactions. Experiments invo... Read More about A photocatalytic impeller reactor for gas phase heterogeneous photocatalysis..

Cellulose II as bioethanol feedstock and its advantages over native cellulose. (2017)
Journal Article
NAGARAJAN, S., SKILLEN, N.C., IRVINE, J.T.S, LAWTON, L.A. and ROBERTSON, P.K. 2017. Cellulose II as bioethanol feedstock and its advantages over native cellulose. Renewable and sustainable energy reviews [online], 77, pages 182-192. Available from: https://doi.org/10.1016/j.rser.2017.03.118

Alternative renewable energy must emerge to sustainably meet the energy demands of the present and future. Current alternatives to fossil fuels are electricity from solar, wind and tidal energies and biofuels. Biofuels, especially bioethanol could be... Read More about Cellulose II as bioethanol feedstock and its advantages over native cellulose..

Effects of temperature and salinity on the production of cell biomass, chlorophyll-a and intra- and extracellular nodularins (NOD) and nodulopeptin 901 produced by Nodularia spumigena KAC 66. (2017)
Journal Article
HAMEED, S., LAWTON, L.A., EDWARDS, C., KHAN, A., FAROOQ, U. and KHAN, F.A. 2017. Effects of temperature and salinity on the production of cell biomass, chlorophyll-a and intra- and extracellular nodularins (NOD) and nodulopeptin 901 produced by Nodularia spumigena KAC 66. Journal of applied phycology [online], 29(4), pages 1801-1810. Available from: https://doi.org/10.1007/s10811-017-1115-5

Nodularia spumigena is one of the dominant toxic cyanobacteria which produce blooms in the Baltic Sea, a brackish water body, particularly in late summer. Nodularia spp. are known to produce hepatotoxic nodularins (NODs) and other bioactive peptides... Read More about Effects of temperature and salinity on the production of cell biomass, chlorophyll-a and intra- and extracellular nodularins (NOD) and nodulopeptin 901 produced by Nodularia spumigena KAC 66..

Hepatotoxic-microcystins in two drinking water reservoirs in the central region of Ghana. (2017)
Journal Article
ADDICO, G.N.D., LAWTON, L. and EDWARDS, C. 2017. Hepatotoxic-microcystins in two drinking water reservoirs in the central region of Ghana. Toxicology and forensic medicine [online], 2(1), pages 1-11. Available from: https://doi.org/10.17140/TFMOJ-2-111

Background: Microcystins are cyclic peptides containing seven amino acids with the condensation of two terminal amino acids of the linear peptide to form a cyclic compound. The cyclic nature of microcystins suggests that they are highly stable in wat... Read More about Hepatotoxic-microcystins in two drinking water reservoirs in the central region of Ghana..

Archaeological medicinal earths as antibacterial agents: the case of the Basel Lemnian sphragides. (2017)
Journal Article
PHOTOS-JONES, E., EDWARDS, C., HANER, F., LAWTON, L., KEAN, C., LEANORD, A. and PERDIKATSIS, V. 2017. Archaeological medicinal earths as antibacterial agents: the case of the Basel Lemnian sphragides. Geological society: special publications. Geology and medicine: historical connections [online], 452, pages 141-153. Available from: https://doi.org/10.1144/SP452.6

This paper presents the scientific investigation of three Lemnian sphragides (terra sigillata), a famed medicinal clay (earth) of antiquity, dated to the 16th-17th century, and presently in the collection of the Museum for the History of Pharmacy of... Read More about Archaeological medicinal earths as antibacterial agents: the case of the Basel Lemnian sphragides..

Mixing regime simulation and cellulose particle tracing in a stacked frame photocatalytic reactor. (2016)
Journal Article
NAGARAJAN, S., STELLA, L., LAWTON, L.A., IRVINE, J.T.S. and ROBERTSON, P.K.J. 2017. Mixing regime simulation and cellulose particle tracing in a stacked frame photocatalytic reactor. Chemical engineering journal [online], 313, pages 301-308. Available from: https://doi.org/10.1016/j.cej.2016.12.016

To sustainably meet the global energy demand, unconventional methods to produce renewable energy must emerge. Biofuels from cellulose (via fermentable sugar production) mediated via photocatalysis provides an alternative to conventional fossil fuels.... Read More about Mixing regime simulation and cellulose particle tracing in a stacked frame photocatalytic reactor..

Comparative assessment of visible light and UV active photocatalysts by hydroxyl radical quantification. (2016)
Journal Article
NAGARAJAN, S., SKILLEN, N.C., FINA, F., ZHANG, G., RANDORN, C., LAWTON, L.A., IRVINE, J.T.S. and ROBERTSON, P.K.J. 2016. Comparative assessment of visible light and UV active photocatalysts by hydroxyl radical quantification. Journal of photochemistry and photobiology A: chemistry [online], 334, pages 13-19. Available from: https://doi.org/10.1016/j.jphotochem.2016.10.034

A simple method for determining hydroxyl radical yields on semiconductor photocatalysts is highly desirable, especially when comparing different photocatalyst materials. This paper reports the screening of a selection of visible light active photocat... Read More about Comparative assessment of visible light and UV active photocatalysts by hydroxyl radical quantification..

Accumulation and detoxication responses of the gastropod Lymnaea stagnalis to single and combined exposures to natural (cyanobacteria) and anthropogenic (the herbicide RoundUp® Flash) stressors. (2016)
Journal Article
LANCE, E., DESPRAT, J., HOLBECH, B.F., GERARD, C., BORMANS, M., LAWTON, L.A., EDWARDS, C. and WIEGAND, C. 2016. Accumulation and detoxication responses of the gastropod Lymnaea stagnalis to single and combined exposures to natural (cyanobacteria) and anthropogenic (the herbicide RoundUp® Flash) stressors. Aquatic toxicology [online], 177, pages 116-124. Available from: https://doi.org/10.1016/j.aquatox.2016.05.024

Freshwater gastropods are increasingly exposed to multiple stressors in the field such as the herbicide glyphosate in Roundup formulations and cyanobacterial blooms either producing or not producing microcystins (MCs), potentially leading to interact... Read More about Accumulation and detoxication responses of the gastropod Lymnaea stagnalis to single and combined exposures to natural (cyanobacteria) and anthropogenic (the herbicide RoundUp® Flash) stressors..

Lack of functional redundancy in the relationship between microbial diversity and ecosystem functioning. (2016)
Journal Article
DELGADO-BAQUERIZO, M., GIARAMIDA, L., REICH, P.B., KHACHANE, A.N., HAMONTS, K., EDWARDS, C., LAWTON, L.A. and SINGH, B.K. 2016. Lack of functional redundancy in the relationship between microbial diversity and ecosystem functioning. Journal of ecology [online], 104(4), pages 936-946. Available from: https://doi.org/10.1111/1365-2745.12585

1. Biodiversity is declining worldwide with detrimental effects on ecosystems. However, we lack a quantitative understanding of the shape of the relationship between microbial biodiversity and ecosystem function (BEF). This limits our understanding o... Read More about Lack of functional redundancy in the relationship between microbial diversity and ecosystem functioning..

Controlled periodic illumination in semiconductor photocatalysis. (2015)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2015. Controlled periodic illumination in semiconductor photocatalysis. Journal of photochemistry and photobiology A: chemistry [online], 319-320, pages 96-106. Available from: https://doi.org/10.1016/j.jphotochem.2015.12.002

Controlled periodic illumination is a hypothesis postulated in the early 1990s for enhancing the efficiency of semiconductor photocatalytic reactions. This technique has been proposed to improve photocatalytic efficiency by the nature of photon intro... Read More about Controlled periodic illumination in semiconductor photocatalysis..

Simultaneous cellulose conversion and hydrogen production assisted by cellulose decomposition under UV-light photcatalysis. (2015)
Journal Article
ZHANG, G., NI, C., HUANG, X., WELGARMAGE, A., LAWTON, L.A., ROBERTSON, P.K.J. and IRVINE, J.T.S. 2016. Simultaneous cellulose conversion and hydrogen production assisted by cellulose decomposition under UV-light photcatalysis. Chemical communications [online], 52, pages 1673-1676. Available from: https://doi.org/10.1039/c5cc09075j

Photocatalytic conversion of cellulose to sugars and carbon dioxide with simultaneous production of hydrogen assisted by cellulose decomposition under UV or solar light irradiation was achieved upon immobilization of cellulose onto a TiO2 photocataly... Read More about Simultaneous cellulose conversion and hydrogen production assisted by cellulose decomposition under UV-light photcatalysis..

Rapid bioassay-guided isolation of antibacterial clerodane type diterpenoid from Dodonaea viscosa (L.) Jaeq. (2015)
Journal Article
KHURRAM, M., LAWTON, L.A., EDWARDS, C., IRITI, M., HAMEED, A., KHAN, M.A., KHAN, F.A. and RAHMAN, S.U. 2015. Rapid bioassay-guided isolation of antibacterial clerodane type diterpenoid from Dodonaea viscosa (L.) Jaeq. International journal of molecular science [online], 16(9), pages 20290-20307. Available from: https://doi.org/10.3390/ijms160920290

Plant extracts are complex matrices and, although crude extracts are widely in use, purified compounds are pivotal in drug discovery. This study describes the application of automated preparative-HPLC combined with a rapid off-line bacterial bioassay... Read More about Rapid bioassay-guided isolation of antibacterial clerodane type diterpenoid from Dodonaea viscosa (L.) Jaeq..

Photocatalytic degradation of eleven microcystin variants and nodularin by TiO2 coated glass microspheres. (2015)
Journal Article
PESTANA, C.J., EDWARDS, C., PRABHU, R., ROBERTSON, P.K.J. and LAWTON, L.A. 2015. Photocatalytic degradation of eleven microcystin variants and nodularin by TiO2 coated glass microspheres. Journal of hazardous materials [online], 300, pages 347-353. Available from: https://doi.org/10.1016/j.jhazmat.2015.07.016

Microcystins and nodularin are toxic cyanobacterial secondary metabolites produced by cyanobacteria that pose a threat to human health in drinking water. Conventional water treatment methods often fail to remove these toxins. Advanced oxidation proce... Read More about Photocatalytic degradation of eleven microcystin variants and nodularin by TiO2 coated glass microspheres..

Sudden flamingo deaths in Kenyan rift valley lakes. (2014)
Journal Article
STRAUBINGER-GANSBERGER, N., GRUBER, M., KAGGWA, M.N., LAWTON, L., ODUOR, S.O. and SCHAGERI, M. 2014. Sudden flamingo deaths in Kenyan rift valley lakes. Wildlife biology [online], 20(3), pages 185-189. Available from: https://doi.org/10.2981/wlb.00018

The East African Rift Valley Lakes Bogoria and Nakuru sometimes host around 75% of the world population of lesser flamingos Phoeniconaias minor. In this area, mysterious flamingo die-offs have occupied researchers for four decades. Recently, cyanobac... Read More about Sudden flamingo deaths in Kenyan rift valley lakes..

Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination. (2014)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2014. Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination. Applied catalysis B: environmental [online], 156-157, pages 398-403. Available from: https://doi.org/10.1016/j.apcatb.2014.03.046

Quantum yields of the photocatalytic degradation of methyl orange under controlled periodic illumination (CPI) have been modelled using existing models. A modified Langmuir-Hinshelwood (L-H) rate equation was used to predict the degradation reaction... Read More about Mathematical modelling of quantum yield enhancements of methyl orange photooxidation in aqueous TiO2 suspensions under controlled periodic UV LED illumination..

The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources. (2014)
Journal Article
TOKODE, O., PRABHU, R., LAWTON, L.A. and ROBERTSON, P.K.J. 2014. The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources. Chemical engineering journal [online], 246, pages 337-342. Available from: https://doi.org/10.1016/j.cej.2014.03.002

The nature of photon interaction and reaction pH can have significant impacts on semiconductor photocatalysis. This paper describes the effect of pH on the photonic efficiency of photocatalytic reactions in the aqueous phase using TiO2 catalysts. The... Read More about The effect of pH on the photonic efficiency of the destruction of methyl orange under controlled periodic illumination with UV-LED sources..

A continuous flow packed bed photocatalytic reactor for the destruction of 2-methylisoborneol and geosmin utilising pelletised TiO2. (2013)
Journal Article
PESTANA, C.J., ROBERTSON, P.K.J., EDWARDS, C., WILHELM, W., MCKENZIE, C. and LAWTON, L.A. 2014. A continuous flow packed bed photocatalytic reactor for the destruction of 2-methylisoborneol and geosmin utilising pelletised TiO2. Chemical engineering journal [online], 235, pages 293-298. Available from: https://doi.org/10.1016/j.cej.2013.09.041

Taste and odour compounds, especially geosmin (GSM) and 2-methylisoborneol (2-MIB), cause major problems in both drinking water and aquaculture industries world-wide. Aquaculture in particular has experienced significant financial losses due to the a... Read More about A continuous flow packed bed photocatalytic reactor for the destruction of 2-methylisoborneol and geosmin utilising pelletised TiO2..

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