C. Chikere
Zinc oxide nanoparticles modified-carbon paste electrode used for the electrochemical determination of Gallic acid.
Chikere, C.; Faisal, N.H.; Kong Thoo Lin, P.; Fernandez, C.
Authors
Professor Nadimul Faisal N.H.Faisal@rgu.ac.uk
Professor
Professor Paul Kong Thoo Lin p.v.s.kong-thoo-lin@rgu.ac.uk
Professor
Dr Carlos Fernandez c.fernandez@rgu.ac.uk
Senior Lecturer
Abstract
Zinc oxide nanoparticles (nano-ZnO) was used to modify carbon paste electrode (CPE) for a fast and sensitive electrochemical determination of gallic acid (GA). The study was carried out using cyclic voltammetry (CV) and differential voltammetry (DPV) techniques, where the nano-ZnO-modified electrode exhibited an efficient and sensitive oxidation of GA. The cyclic voltammetric result showed a significant enhancement of the peak current from 250?A to about 410?A. The electrochemical behaviour of GA on the nano-ZnO modified carbon paste electrode was studied using DPV, showing a sensitivity of the electrode in a concentration range of 1 x 10?6 to 5.0 x 10?5 mol L?1, with a correlation coefficient R2 of 0.9968 and a limit of detection of 1.86 x 10?7 mol L?1 (S/N =3). The proposed electrode was used successfully for the determination of GA in red wine with recoveries of 103%.
Citation
CHIKERE, C., FAISAL, N.H., KONG THOO LIN, P. and FERNANDEZ, C. 2019. Zinc oxide nanoparticles modified-carbon paste electrode used for the electrochemical determination of Gallic acid. Journal of physics: conference series [online], 1310: proceedings of 2018 Applied nanotechnology and nanoscience international conference (ANNIC 2018), 22-24 October 2018, Berlin, Germany, article ID 012008. Available from: https://doi.org/10.1088/1742-6596/1310/1/012008
Journal Article Type | Conference Paper |
---|---|
Conference Name | 2018 Applied nanotechnology and nanoscience international conference (ANNIC 2018) |
Conference Location | Berlin, Germany |
Acceptance Date | Aug 6, 2019 |
Online Publication Date | Oct 8, 2019 |
Publication Date | Oct 8, 2019 |
Deposit Date | Oct 11, 2019 |
Publicly Available Date | Oct 11, 2019 |
Journal | Journal of Physics: Conference Series |
Print ISSN | 1742-6588 |
Electronic ISSN | 1742-6596 |
Publisher | IOP Publishing |
Peer Reviewed | Peer Reviewed |
Volume | 1310 |
Article Number | 012008 |
DOI | https://doi.org/10.1088/1742-6596/1310/1/012008 |
Keywords | Zinc oxide nanoparticles; Gallic acid; Cyclic voltammetry; Differential pulse voltammetry; Electrochemistry |
Public URL | https://rgu-repository.worktribe.com/output/641735 |
Files
CHIKERE 2019 Zinc oxide (VOR)
(782 Kb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by/4.0/
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